Synthesis and Properties of Boron(III)-Coordinated Subbacteriochlorins
Synthesis and Properties of Boron(III)-Coordinated Subbacteriochlorins
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硼(III)配位的亚菌绿素的合成及性质
DOI：
10.1021/ja200669a
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发表时间：
2011
期刊：
影响因子：
--
通讯作者：
A.
中科院分区：
文献类型：
--
作者：
Hayashi;S.;Tsurumaki;E.;Inokuma;Y.;Kim;P.;Sung;Y.M.;Kim;D.;Osuka;A.
亚细菌氯由亚卟啉与雷尼镍氢化而成，由于14π-重氮环烯的环路而具有温和的芳香性，并表现出特征的蓝移Soret带、增强的荧光光谱和高的氧化电位。
Subbacteriochlorins, which were prepared via hydrogenation of subporphyrins with Raney nickel, are modestly aromatic due to 14π-diazaannulenic circuit and exhibit characteristic blue-shifted Soret-like bands, intensified fluorescence spectra, and high oxidation potentials.