A Co8 metallacycle stabilized by double anion-π interactions
A Co8 metallacycle stabilized by double anion-π interactions
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DOI：
10.1039/c9cc04151f
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发表时间：
2019-10-21
影响因子：
4.9
通讯作者：
Dunbar, Kim R.
中科院分区：
文献类型：
--
作者：
Alexandropoulos, Dimitris, I;Dolinar, Brian S.;Dunbar, Kim R.
在 2,2-联嘧啶 (bpym) 配体存在下，Co-II 离子的自组装反应产生双核和八核阳离子，其核性由阴离子和配体之间的氢键与阴离子-pi 相互作用控制。
Self-assembly reactions of Co-II ions in the presence of the 2,2-bipyrimidine (bpym) ligand produced both a dinuclear and an octanuclear cation with the nuclearity being governed by hydrogen-bonding versus anion-pi interactions between the anions and the ligands.