A Method for the Selective Hydrogenation of Alkenyl Halides to Alkyl Halides
A Method for the Selective Hydrogenation of Alkenyl Halides to Alkyl Halides
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DOI：
10.1021/ja502885c
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发表时间：
2014-05-14
影响因子：
15
通讯作者：
Herzon, Seth B.
中科院分区：
文献类型：
--
作者：
King, Sandra M.;Ma, Xiaoshen;Herzon, Seth B.
介绍了一种将卤代烯烃选择性加氢为卤代烷的一般方法。氟、氯、溴、碘和宝石二卤烯是转化的可行底物。氢化反应的选择性与氢原子转移途径的还原反应一致。
A general method for the selective hydrogenation of alkenyl halides to alkyl halides is described. Fluoro, chloro, bromo, iodo, and gem-dihaloalkenes are viable substrates for the transformation. The selectivity of the hydrogenation is consistent with reduction by a hydrogen atom transfer pathway.