Synthesis of (+)‐Strigol and (+)‐Orobanchol, the Germination Stimulants, and Their Stereoisomers by Employing Lipase‐Catalyzed Asymmetric Acetylationas the Key Step
Synthesis of (+)‐Strigol and (+)‐Orobanchol, the Germination Stimulants, and Their Stereoisomers by Employing Lipase‐Catalyzed Asymmetric Acetylationas the Key Step
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以脂肪酶催化不对称乙酰化为关键步骤合成发芽刺激剂(+)-独脚金醇和(+)-列班胆及其立体异构体
DOI：
10.1002/(sici)1099-0690(199909)1999:9
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发表时间：
1999
影响因子：
2.8
通讯作者：
K. Mori
中科院分区：
文献类型：
--
作者：
K. Hirayama;K. Mori
以（±）-3为原料，通过脂肪酶催化拆分得到3的对映异构体，合成了（+）-独脚金醇（1）、（+）-列当醇（2）及其立体异构体[2′-表独脚金醇（1′）、ent-1、ent-1′，2′-表列当醇（2′）、4-表列当醇（2′′）和4，2′-二表列当醇（2′）]。
The potent seed germination stimulants (+)-strigol (1), (+)-orobanchol (2) and their stereoisomers [2′-epistrigol (1′), ent-1, ent-1′, 2′-epiorobanchol (2′), 4-epiorobanchol (2′′) and 4, 2′-bisepiorobanchol (2′′′)] were prepared from the enantiomers of 3, which were obtainable by lipase-catalyzed enantiomer separation of (±)-3.