Highly efficient chromatographic resolution of alpha,alpha'-dihydroxybiaryls.

Highly efficient chromatographic resolution of alpha,alpha'-dihydroxybiaryls.
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高效色谱分离 α,α-二羟基联芳基化合物。

DOI:
10.1021/ol052309z
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发表时间:
2005
期刊:
Organic letters.
影响因子:
--
通讯作者:
Li,Tingyu
Li,Tingyu
中科院分区:
--
文献类型:
--
作者:
Huang,Junmin;Li,Tingyu

文献摘要

相似文献

许多α,α‘-二羟基联芳基的分离系数高达115,用容易获得的氨基酸衍生物制成的单一手性固定相。该固定相对联苯类化合物工作良好。它对较大的双芳烃化合物非常有效,例如联萘型化合物。
Separation factors as high as 115 were observed for the chromatographic resolution of many α,α‘-dihydroxybiaryls with a single chiral stationary phase made from readily available amino acid derivatives. The stationary phase works well for biphenyl-type compounds. It works extremely well for larger bis-aromatic compounds, such as binaphthyl-type compounds.