Rules for transition rates in nonequilibrium steady states.
Rules for transition rates in nonequilibrium steady states.
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非平衡稳态中的转变率规则。
DOI：
10.1103/physrevlett.92.150601
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发表时间：
2004
影响因子：
8.6
通讯作者：
R. Evans
中科院分区：
文献类型：
--
作者：
R. Evans
正如正则系综中的跃迁速率必须遵守详细平衡的原则一样，在驱动稳态中，跃迁速率也存在限制。我推导出这些限制，最大信息熵的推断，并将其应用到驱动扩散和剪切晶格流体的稳定状态。由此产生的合奏可以潜在地解释非平衡相行为，并为稳定的剪切，引起应力介导的长程相互作用。
Just as transition rates in a canonical ensemble must respect the principle of detailed balance, constraints exist on transition rates in driven steady states. I derive those constraints, by maximum information-entropy inference, and apply them to the steady states of driven diffusion and a sheared lattice fluid. The resulting ensemble can potentially explain nonequilibrium phase behavior and, for steady shear, gives rise to stress-mediated long-range interactions.