Improved transparency-nonlinearity trade-off with boroxine-based octupolar molecules
Improved transparency-nonlinearity trade-off with boroxine-based octupolar molecules
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DOI：
10.1039/b308664j
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发表时间：
2003-01-01
影响因子：
4.9
通讯作者：
Vaultier, M
中科院分区：
文献类型：
--
作者：
Alcaraz, G;Euzenat, L;Vaultier, M
设计了一系列由硼砂骨架衍生的八极性分子，并通过溶液中的谐波光散射实验研究了它们的光学非线性；发现分子在近紫外可见区具有优异的透明度（λ (max)小于或等于280 nm）和显著的一阶超极化(高达β (0) = 56 X 10(-30) esu)。
A series of octupolar molecules derived from the boroxine framework were designed and their optical nonlinearities were investigated by performing harmonic light scattering experiments in solution; the molecules were found to combine excellent transparency in the near UV-visible region (lambda(max) less than or equal to 280 nm) and significant first-order hyper-polarisabilities (up to beta(0) = 56 X 10(-30) esu).