Synthesis of 1,1‘-Diphospha[4]ferrocenophanes by Molybdenum-Catalyzed Ring-Closing Metathesis
Synthesis of 1,1‘-Diphospha[4]ferrocenophanes by Molybdenum-Catalyzed Ring-Closing Metathesis
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钼催化闭环复分解合成 1,1-二磷[4]二茂铁
DOI:
10.1021/om021058k
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发表时间:
2003
期刊:
影响因子:
2.8
通讯作者:
Tamio Hayashi
中科院分区:
文献类型:
--
作者:
M. Ogasawara;T. Nagano;Tamio Hayashi
A variety of 1,1‘-diphospha[4]ferrocenophanes were prepared in good to moderate yield with the interannular ring-closing metathesis reaction of diallyl-1,1‘-diphosphaferrocenes using the Schrock's molybdenum-carbene catalyst. The Grubbs' ruthenium metathesis catalyst was found inactive for these Lewis basic phosphorus-containing substrates.