Pulse and AC Impedance Studies of the Electrochemical Systems of Titanium in LiCl ‐ KCl Eutectic Melt at 743 K
Pulse and AC Impedance Studies of the Electrochemical Systems of Titanium in LiCl ‐ KCl Eutectic Melt at 743 K
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743 K 下 LiCl - KCl 共晶熔体中钛电化学体系的脉冲和交流阻抗研究
DOI：
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发表时间：
1988
期刊：
影响因子：
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通讯作者：
B. Tremillon
中科院分区：
文献类型：
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作者：
D. Ferry;G. Picard;B. Tremillon
本文用脉冲法和交流阻抗法研究了钛在LiCl-KCl共晶熔体中的电化学体系。阻抗测量Ti 3 +/Ti（IV）体系为可逆体系，Ti 3 +/Ti 2+体系为准可逆体系，Ti 2+沉积金属钛为不可逆体系。与这些氧化还原系统相关的动力学常数也已被确定为扩散层的厚度，双电层电容和电解质电阻。
The electrochemical systems of titanium in LiCI-KCI eutectic melt have been investigated by means of pulse techniques and A.C. impedance measurements. Ti 3 +/Ti(IV) electrochemical system appears reversible while Ti 3 +/Ti2+ is quasi-reversible and metallic titanium deposition from Ti2+ is irreversible. Kinetic constants related to these redox systems have been determined as also the thickness of the diffusion layer, the double layer capacitance and the electrolyte resistance.