Iodine-catalyzed efficient 2-arylsulfanylphenol formation from thiols and cyclohexanones

Iodine-catalyzed efficient 2-arylsulfanylphenol formation from thiols and cyclohexanones
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碘催化硫醇和环己酮有效形成 2-芳基硫基苯酚

DOI:
10.1039/c3gc41671b
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发表时间:
2013-01-01
期刊:
影响因子:
9.8
通讯作者:
Deng, Guo-Jun
Deng, Guo-Jun
中科院分区:
化学1区
文献类型:
--
作者:
Liao, Yunfeng;Jiang, Pengcheng;Deng, Guo-Jun

文献摘要

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介绍了一种由硫醇和环己酮合成2-芳硫基苯酚的新方法。碘被用作这种转化的有效催化剂。通过脱氢和互变异构化反应,使用环己酮作为苯酚源。
A novel method for the formation of 2-arylsulfanylphenols from thiols and cyclohexanones is described. Iodine was used as an effective catalyst for this kind of transformation. Cyclohexanones were used as a phenol source via a dehydrogenation and tautomerization reaction.