Further verification of fluorescence-detected circular dichroism

Further verification of fluorescence-detected circular dichroism
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荧光检测圆二色性的进一步验证

DOI:
10.1021/ja00546a029
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发表时间:
1980
影响因子:
15
通讯作者:
D. Turner
D. Turner
中科院分区:
化学1区
文献类型:
--
作者:
E. W. Lobenstine;D. Turner

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他们注意到荧光将被极化,因此必须考虑光选择效应。结果表明,对于沿k方向传播的激发光,光电倍增管的方向与其沿着j轴垂直,其前面有起偏器,测量信号SF为7,8
They noted that the fluorescence will be polarized, and therefore photoselection effects mustbe considered. A detailed theory for this case has been derived^ One result is that for an excitation beam propagating in thek direction, with a photomultiplier or-iented perpendicular to this along the j axis, with a polarizer in front of it, the measured signal, SF, is7, 8