Synthesis, characterization and photoluminescent properties of platinum complexes with novel bis(imidazoline) pincer ligands
Synthesis, characterization and photoluminescent properties of platinum complexes with novel bis(imidazoline) pincer ligands
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DOI：
10.1016/j.tetlet.2006.05.096
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发表时间：
2006-07-17
影响因子：
1.8
通讯作者：
Song, Mao-Ping
中科院分区：
文献类型：
--
作者：
Hao, Xin-Qi;Gong, Jun-Fang;Song, Mao-Ping
首次合成了手性C-2对称双咪唑啉钳形配体2a-d。这些配体在无水乙酸中与K2 PtCl 4直接环铂化，得到相应的环铂钳形配合物3a-d。本文报道了铂配合物3d的X射线单晶结构，并对其光致发光性质进行了初步研究。(c)2006爱思唯尔有限公司保留所有权利。
Chiral C-2-symmetric bis(imidazoline) pincer ligands 2a-d have been synthesized for the first time. Direct cycloplatination of these ligands with K2PtCl4 in dry acetic acid afforded the corresponding cycloplatinated pincer complexes 3a-d. The X-ray single-crystal structure of platinum complex 3d and the preliminary studies on the photoluminescent properties of 3 are reported. (c) 2006 Elsevier Ltd. All rights reserved.