Tris(phenyl 2-pyridyl ketone oxime-κN,N')cadmium(II) dinitrate.
Tris(phenyl 2-pyridyl ketone oxime-κN,N')cadmium(II) dinitrate.
复制标题
DOI：
10.1107/s1600536809017073
复制
发表时间：
2009-05-14
期刊：
影响因子：
--
通讯作者：
Liu GX
中科院分区：
文献类型：
--
作者：
Yan J;Liu GX
标题化合物[Cd（C12 H10 N2 O）3]（NO3）2中的Cd原子采用畸变八面体构型，被来自三个不同苯基-2-吡啶酮肟配体的六个N原子连接。在晶体结构中，分子间O-H O和C-H O氢键将分子连接成沿沿着延伸的链结构[100]。链通过货车德瓦尔斯力进一步连接成三维超分子结构。
The Cd atom in the title compound, [Cd(C12H10N2O)3](NO3)2, adopts a distorted octahedral geometry, being ligated by six N atoms from three different phenyl-2-pyridyl ketone oxime ligands. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a chain structure propagating along [100]. The chains are further linked into a three-dimensional supramolecular structure via van der Waals forces.