Dinuclear Mn(I) Complexes with Phosphido and Hydrido Bridges: Synthesis, Reactivity, and Hydrogenative Catalysis
Dinuclear Mn(I) Complexes with Phosphido and Hydrido Bridges: Synthesis, Reactivity, and Hydrogenative Catalysis
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具有磷脂桥和氢桥的双核 Mn(I) 配合物：合成、反应性和氢化催化
DOI：
10.1002/chem.202300518
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发表时间：
2023
期刊：
影响因子：
--
通讯作者：
Abhyankar, Preshit C.
中科院分区：
文献类型：
--
作者：
Lacy, David C.;Abhyankar, Preshit C.
最近又发现了一类有机锰加氢催化剂。它们是简单的含磷(Pr2−)和氢键(H−)的双核锰(I)羰基化合物。这类化合物自上世纪60年代S发现以来，具有丰富的配位化学性质和反应活性。鉴于它们最近发现的催化应用潜力，有必要重新审视这类化合物。因此，这篇综述全面涵盖了这类有趣的分子的合成、反应活性和催化作用。
A class of organomanganese hydrogenation catalysts was recently rediscovered. These are simple dinuclear Mn(I) carbonyl compounds with phosphido (PR2−) and hydrido (H−) bridges. This class of compounds has been known since the 1960’s, and they have rich coordination chemistry and reactivity. Given their recently discovered potential for catalytic applications, a fresh look at this class of compounds was necessary. Hence, this Review comprehensively covers the synthesis, reactivity, and catalysis of this interesting class of molecules.