Carbon-carbon bond formation via homocoupling reaction of substrates with a broad diversity in water using Pd(OAc)2 and agarose hydrogel as a bioorganic ligand, support and reductant
Carbon-carbon bond formation via homocoupling reaction of substrates with a broad diversity in water using Pd(OAc)2 and agarose hydrogel as a bioorganic ligand, support and reductant
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DOI：
10.1016/j.molcata.2011.08.010
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发表时间：
2011-09-01
影响因子：
--
通讯作者：
Kazemi, Faezeh
中科院分区：
文献类型：
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作者：
Firouzabadi, Habib;Iranpoor, Nasser;Kazemi, Faezeh
本研究以Pd（OAc）（2）为预催化剂，琼脂糖为可降解的生物有机配体、载体和还原剂，建立了一种新的催化体系，用于不同的卤代芳烃、β-溴苯乙烯、苯硼酸和苯乙炔等为底物的自偶联反应。反应在室温下进行得很顺利，产率高
In this study, we have presented a new catalytic system in which Pd(OAc)(2) has been used as a pre-catalyst and agarose as a degradable bioorganic ligand, support and reductant for carbon-carbon bond formation via homocoupling reaction of different aryl halides, beta-bromo styrene, phenylboronic acid and phenylacetylene as the substrates. The reactions proceeded smoothly with high yields at temperature