Emergence of Magnetic States in Pr2Fe(4-x)Co(x)Sb5 (1 < x < 2.5).
Emergence of Magnetic States in Pr2Fe(4-x)Co(x)Sb5 (1 < x < 2.5).
复制标题
Pr2Fe(4-x)Co(x)Sb5 (1 < x < 2.5) 中出现磁性。
作者：
Pilanda Watkins;Kyle J. Pujol;Katherine A. Benavides;J. Burnett;Jenny K. Hedlund;Julia Bykova;G. McCandless;A. Walker;J. Chan
Single crystals of Pr2Fe(4-x)Co(x)Sb5 (1 < x < 2.5) were grown from a Bi flux and characterized by X-ray diffraction. The compounds adopt the La2Fe4Sb5 structure type (I4/mmm). The structure of Pr2Fe(4-x)Co(x)Sb5 (1 < x < 2.5) contains a network of transition metals forming isosceles triangles. The x ∼ 1 analogue is metallic and exhibits a magnetic transition at T1 ≈ 25 K. The magnetic moment obtained from the Curie-Weiss fit is 11.49(4) μ(B), which is larger than the spin-only Pr(3+) moment. The x ∼ 2 analogue orders magnetically at T1 ≈ 80 and T2 ≈ 45 K. This is the first case of the substitution of Co into the La2Fe4Sb5 structure type, evidenced by the increased concentration of dopant with decreased lattice parameters coupled with a change in the transition temperature with a change in the cobalt concentration. The added complexity in the magnetic behavior of the x ∼ 1 and 2 analogues indicates that the increased concentration of Co invokes an additional magnetic contribution of the transition metal in the sublattice. Furthermore, X-ray photoelectron spectroscopy measurements support the change in the oxidation states of transition metals with increasing cobalt concentration.
