Cyclic polyesters: synthetic approaches and potential applications

Cyclic polyesters: synthetic approaches and potential applications
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DOI:
10.1039/c0py00102c
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发表时间:
2011-01
期刊:
影响因子:
4.6
通讯作者:
Jessica N. Hoskins;Scott M. Grayson
Jessica N. Hoskins;Scott M. Grayson
中科院分区:
化学2区
文献类型:
--
作者:
Jessica N. Hoskins;Scott M. Grayson

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综述了制备环状聚酯的合成策略。线性聚酯和支链聚酯广泛应用于生物医学和材料领域,但环状聚酯的制备难度限制了它们的开发。最近开发的合成方法补充了以前的技术,并承诺为未来的研究增加循环聚酯的可用性。讨论了每种方法的相对优缺点,以及环状聚合物所表现出的一些独特的物理性质。
The synthetic strategies that have been developed for the preparation of cyclic polyesters are reviewed. While linear and branched polyesters are used extensively for biomedical and materials applications, the synthetic difficulty of preparing cyclic polyesters has limited their exploration. Recently synthetic methodologies have been developed which compliment previous techniques, and promise to increase the availability of cyclic polyesters for future studies. The relative advantages and disadvantages of each approach are discussed, as well as some of the unique physical properties demonstrated by cyclic polymers.