Straightforward synthesis and structure of a new starting material for niobium cluster phases: [Nb6Cl(i)12(CH3OH)a4Cla2].6CH3OH.
Straightforward synthesis and structure of a new starting material for niobium cluster phases: [Nb6Cl(i)12(CH3OH)a4Cla2].6CH3OH.
复制标题
铌簇相的新起始材料的直接合成和结构：[Nb6Cl(i)12(CH3OH)a4Cla2].6CH3OH。
DOI：
10.1021/ic061020q
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发表时间：
2006
影响因子：
4.6
通讯作者：
M. Köckerling
中科院分区：
文献类型：
--
作者：
L. F. Piedra;M. Köckerling
新簇化合物[Nb(6)Cl(i)(12)(CH(3)OH)(A)(4)Cl(A)(2)]的新、快速、直接的合成路线。6CH(3)OH利用四氰硼酸盐的特殊溶解度，确定了该化合物的单晶x射线结构，是制备新簇相的有希望的起始材料。
A new, fast, and straightforward synthetic route for the new cluster compound [Nb(6)Cl(i)(12)(CH(3)OH)(a)(4)Cl(a)(2)].6CH(3)OH, taking advantage of the special solubility properties of tetracyanoborate salts has been established, and the single-crystal X-ray structure of this compound, which is a promising starting material for new cluster phases, has been determined.