Exploring anodes for calcium-ion batteries
Exploring anodes for calcium-ion batteries
复制标题
探索钙离子电池阳极
DOI：
10.1039/d2ma01034h
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发表时间：
2023
影响因子：
5
通讯作者：
Tinker H
中科院分区：
文献类型：
--
作者：
Tinker H
随着工业开始转向“超越锂离子”的研究和开发时代，钙离子电池作为替代能量存储系统已被越来越多地探索。然而，使用钙金属作为电池的阳极存在许多问题，包括不能从金属上剥离离子，以及产生非活性钝化层。围绕钙离子电池进行的大多数研究都集中在电解质和阴极研究上，而很少关注阳极，部分原因是解决其挑战的复杂性和难度。在此，本文将讨论钙的问题，包括其缺乏可逆性和固体电解质界面的形成，以及探索已被利用的替代阳极材料，指出其可行性和未来的前景。
Calcium ion batteries have been increasingly explored as an alternative energy storage system as industry begins to manoeuvre towards an age of ‘Beyond lithium-ion’ research and development. However, using calcium metal as the battery's anode presents a multitude of issues, including the inability to strip ions off the metal, and the creation of an inactive passivation layer. Most research conducted around calcium ion batteries focuses on the electrolytic and cathodic study, whereas little focuses on the anode, due in part to the complexity and difficulty in resolving its challenges. Herein, this review will address the issues calcium has, including its lack of reversibility and solid electrolyte interface formation, as well as explore the alternative anode materials that have been utilised, noting their viability and future prospects.