Transition from normal to flowerlike micelles

Transition from normal to flowerlike micelles
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DOI:
10.1021/jp000248a
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发表时间:
2000-11-09
影响因子:
3.3
通讯作者:
Chatterji, PR
Chatterji, PR
中科院分区:
化学3区
文献类型:
--
作者:
Maiti, S;Chatterji, PR

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对一系列通式为C_(16)EO_(20)Cn '(n' = 0-16)的三嵌段两亲分子的界面性质和溶液性质进行了系统的研究,结果表明,只有当n'大于或等于8时,才形成花状胶束。这与成环自由能的热力学计算是一致的。
A systematic investigation of the interfacial and solution properties of a series of triblock amphiphiles with the general formula C16EO20Cn', n' = 0-16, indicates that flowerlike micelles are formed only when n' greater than or equal to 8. This is consistent with the thermodynamic calculations of the free energy of looping.