Photocatalytic aerobic oxidation/semipinacol rearrangement sequence: a concise route to the core of pseudoindoxyl alkaloids
Photocatalytic aerobic oxidation/semipinacol rearrangement sequence: a concise route to the core of pseudoindoxyl alkaloids
复制标题
光催化有氧氧化/半频哪醇重排序列：通往假吲哚酚生物碱核心的简洁途径
DOI：
10.1016/j.tetlet.2014.06.102
复制
发表时间：
2014-08-13
影响因子：
1.8
通讯作者：
Xiao, Wen-Jing
中科院分区：
文献类型：
--
作者：
Ding, Wei;Zhou, Quan-Quan;Xiao, Wen-Jing
成功地建立了一种可见光诱导的光催化好氧氧化/半片呐醇重排反应。这种方法允许在温和的反应条件下，将广泛的吲哚有效地转化为合成上重要的2，2-二取代吲哚-3-酮，这是伪吲哚生物碱的核心结构。(C)爱思唯尔有限公司出版的2014年。
A visible light-induced photocatalytic aerobic oxidation/semipinacol rearrangement has been successfully developed. This methodology allows for efficient conversion of a wide range of indoles into the synthetically significant 2,2-disubstituted indolin-3-ones, the core structure of pseudoindoxyl alkaloids, under mild reaction conditions. (C) 2014 Published by Elsevier Ltd.