Large anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex.

Large anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex.
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DOI:
10.1002/anie.200700629
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发表时间:
2007-09
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影响因子:
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通讯作者:
Qiong Ye;Hong Zhao;Zhirong Qu;D. Fu;R. Xiong;Yi Cui;T. Akutagawa;P. Chan;Takayoshi Nakamura
Qiong Ye;Hong Zhao;Zhirong Qu;D. Fu;R. Xiong;Yi Cui;T. Akutagawa;P. Chan;Takayoshi Nakamura
中科院分区:
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文献类型:
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作者:
Qiong Ye;Hong Zhao;Zhirong Qu;D. Fu;R. Xiong;Yi Cui;T. Akutagawa;P. Chan;Takayoshi Nakamura

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不同的方向:在烯烃铜络合物(见结构式,右)中观察到巨大且永久的各向异性(见图片,左)。这种现象可能是由于晶体中的弱D-溴相互作用。
(Chemical Equation Presented) Different directions: Huge and permanent anisotropy (see picture, left) was observed in an olefin copper complex (see structural formula, right). This phenomenon is likely due to weak D⋯ Br interactions in the crystal.