Zwitterionic Polyelectrolytes: A Review
Zwitterionic Polyelectrolytes: A Review
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两性离子聚电解质：综述
DOI：
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发表时间：
2007
期刊：
影响因子：
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通讯作者：
Meenakshi Singh
中科院分区：
文献类型：
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作者：
Paresh Kumar Singh;V. Singh;Meenakshi Singh
摘要 综述了两性离子聚电解质领域的最新进展。此类聚电解质自 1952 年首次合成以来只有 50 年的历史。聚羧基甜菜碱、聚磺基甜菜碱、聚磷酸甜菜碱和其他一些两性离子材料组成了此类聚合物。在当前寻找“仿生”材料的过程中，这一类尤为重要。多两性离子的响应特性对各种外部刺激具有特异性、敏感性和瞬时性，本文对此进行了综述。综述了聚两性电解质和聚甜菜碱（均聚物、共聚物、嵌段聚合物）的合成。此类材料在固态导电材料、色谱材料和其他应用中的开发已被纳入。对溶液性质、抗聚电解特性和不同类别电解质的影响进行了定性和定量的广泛讨论，提供了对此类材料的重要性和相关性的深入了解，嵌段聚合物也形成可逆的“精神分裂”胶束。
Abstract Recent progress in the field of zwitterionic polyelectrolytes is reviewed. This class of polyelectrolytes is only five decades old, since the first synthesis was in 1952. Polycarboxybetaines, polysulfobetaines, polyphosphobetaines and a few more zwitterionic materials compose this class of polymers. In the current search for ‘biomimicking’ materials, this class is particularly important. The responsive properties of polyzwitterions are specific, sensitive and instantaneous to a wide variety of external stimuli, which has been reviewed in this article. The synthesis of polyampholytes and polybetaines (homopolymers, copolymers, block polymers) are reviewed. The exploitation of such materials in solid state conducting materials, chromatographic materials and other applications has been incorporated. The extensive discussion on solution properties, antipolyelectrolytic characteristics and influence of varying class of electrolytes has been qualitative as well as quantitative providing an insight into the importance and relevance of such materials, the block polymers form reversible ‘schizophrenic’ micelles also.