Lipase-catalyzed Enantioselective Acylation in a Halogen Free Ionic Liquid Solvent System
Lipase-catalyzed Enantioselective Acylation in a Halogen Free Ionic Liquid Solvent System
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无卤离子液体溶剂体系中脂肪酶催化的对映选择性酰化
DOI：
10.1246/cl.2003.654
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发表时间：
2003
影响因子：
1.6
通讯作者：
Y. Nishimura
中科院分区：
文献类型：
--
作者：
T. Itoh;Nozomi Ouchi;S. Hayase;Y. Nishimura
以几种咪唑烷基硫酸盐为反应介质，研究了脂肪酶催化的对映选择性酯交换反应。在所使用的条件下成功地获得了所需的光学纯的乙酸酯，尽管反应速率低于咪唑四氟硼酸盐。
Lipase-catalyzed enantioselective transesterification was demonstrated using several types of imidazolium alkyl sulfate as a reaction medium. The desired optically pure acetate was successfully obtained under the conditions used, although reaction rate was inferior to that in imidazolium tetrafluoroborate.