Structural and Redox Interconversions of Sulfur Ligands of Transition Metal Complexes
Structural and Redox Interconversions of Sulfur Ligands of Transition Metal Complexes
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DOI：
10.1080/02603594.2023.2200174
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发表时间：
2023-04
影响因子：
5.4
通讯作者：
W. T. M. Seo;Emily Y. Tsui
中科院分区：
文献类型：
--
作者：
W. T. M. Seo;Emily Y. Tsui
摘要过渡金属和硫之间的相互作用在生物和地质系统中的相关性以及在催化和能量储存方面的潜在应用一直是人们研究的热点。具有含硫配体的络合物可以经历以硫为中心以及以金属为中心的氧化还原转化。硫也容易与其它硫中心链合以形成多硫基序。在此，描述了具有含硫配体（硫基、多硫基和多硫酰氨基）的金属络合物的显著实例的合成和结构。硫为中心的氧化还原方面，包括光谱和结构的考虑，以及未来的研究机会是突出的。图形摘要
ABSTRACT The interactions between transition metals and sulfur have long been studied for potential applications in catalysis and energy storage and due to the relevance of these motifs in biological and geological systems. Complexes with sulfur-containing ligands can undergo redox transformations centered on sulfur as well as at the metal. Sulfur also readily catenates with other sulfur centers to form polysulfur motifs. Here, the synthesis and structures of notable examples of metal complexes with sulfur-containing ligands (sulfido, polysulfido, and polysulfanido) are described. Aspects of sulfur-centered redox, including spectroscopic and structural considerations, and future research opportunities are highlighted. GRAPHICAL ABSTRACT