Novel Alkoxide Cluster Topologies Featuring Rare Seesaw Geometry at Transition Metal Centers
Novel Alkoxide Cluster Topologies Featuring Rare Seesaw Geometry at Transition Metal Centers
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DOI：
10.1002/chem.201302558
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发表时间：
2013-09-09
影响因子：
4.3
通讯作者：
Groysman, Stanislav
中科院分区：
文献类型：
--
作者：
Bellow, James A.;Fang, Dong;Groysman, Stanislav
文摘谨慎!化学家：M= Cr - Co合成了具有过渡金属中心罕见的跷跷板几何形状的新型簇[M2Li2Cl2 (OR) 4]。使用立体阻碍烷氧化物配体，以及在结构中包含锂离子，加强了这种极不寻常的配置。
Abstract Caution! Chemists playing: Novel clusters of the form [M2Li2Cl2 (OR) 4] featuring rare seesaw geometry at the transition metal centers were synthesized for M= Cr Co. The use of sterically hindering alkoxide ligands, as well as the inclusion of lithium ions in the structures enforces this highly unusual configuration.