EFFECT OF BN/Ti RATIO ON THE REACTION SYNTHESIS OF TiB2-TiNx CERAMICS

EFFECT OF BN/Ti RATIO ON THE REACTION SYNTHESIS OF TiB2-TiNx CERAMICS
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DOI:
10.1142/s0217979209060646
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发表时间:
2009-03
影响因子:
1.7
通讯作者:
Lei Zhan;P. Shen;Q. Jiang
Lei Zhan;P. Shen;Q. Jiang
中科院分区:
物理与天体物理4区
文献类型:
--
作者:
Lei Zhan;P. Shen;Q. Jiang

文献摘要

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The effects of BN/Ti molar ratio on the self-propagating high-temperature synthesis (SHS) reaction behaviors and final products in the Ti-BN system were experimentally investigated. With an increase in the BN/Ti ratio, the combustion temperature and wave velocity first increase and then decrease with the maximum values displaying at BN/Ti=0.67. A substoichiometric TiN1-x was obtained for BN/Ti<0.67, and a stoichiometric one was produced for BN/Ti=0.67. Moreover, the microstructure photographs of the products reveal that with the increase of the BN/Ti ratio, the grains of the ceramic phases tend to be finer.