One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence.
One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence.
复制标题
使用串联烯烃交叉复分解/烯丙碳酸酯还原顺序进行一锅末端烯烃同系化。
DOI：
10.1039/b709754a
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发表时间：
2007
期刊：
影响因子：
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通讯作者：
Marks,LucasR
中科院分区：
文献类型：
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作者：
Comins,DanielL;Dinsmore,JasonM;Marks,LucasR
利用烯烃交叉复分解，然后进行钯介导的烯丙碳酸酯还原，开发了末端烯烃的一碳同系化；使用各种底物来证明反应范围，产率范围为 65% 至 86%。
A one-carbon homologation of terminal alkenes has been developed utilizing an olefin cross-metathesis followed by a palladium-mediated allylic carbonate reduction; various substrates were used to demonstrate the scope of the reaction, with yields ranging from 65 to 86%.