COMPLEXES OF RIBOFLAVIN WITH SILVER AND OTHER METAL IONS

COMPLEXES OF RIBOFLAVIN WITH SILVER AND OTHER METAL IONS
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DOI:
10.1016/0006-3002(61)90005-1
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发表时间:
1961-01-01
期刊:
BIOCHIMICA ET BIOPHYSICA ACTA
影响因子:
--
通讯作者:
METZLER, DE
METZLER, DE
中科院分区:
其他
文献类型:
--
作者:
BAARDA, IF;METZLER, DE

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本文用分光光度法、pH滴定法、连续变化法、超离心法和固体结晶物分析法研究了红色可溶性核黄素银配合物。结果表明,银取代了黄素的3号氢原子,形成了银与黄素的高分子配合物。该体系可以近似地描述为由具有溶度积的胶体复合物组成
The red, soluble silver riboflavin complex has been studied by means of spec-trophotometry, pH titrations, the method of continuous variation, ultracentrifugation and analysis of the solid crystalline material. It is concluded that the number 3 hydrogen atom of the flavin is replaced by silver to give a highly polymerized complex containing silver and flavin in a 11 ratio. The system can be described approximately as consisting of a colloidal complex with a solubility product