Palladium(II)-catalyzed direct conversion of methyl arenes into aromatic nitriles.
Palladium(II)-catalyzed direct conversion of methyl arenes into aromatic nitriles.
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DOI：
10.1002/anie.201305731
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发表时间：
2013-08
影响因子：
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通讯作者：
Zhibin Shu;Yuxuan Ye;Yifan Deng;Yan Zhang;J. Wang
中科院分区：
文献类型：
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作者：
Zhibin Shu;Yuxuan Ye;Yifan Deng;Yan Zhang;J. Wang
从甲基制腈：以Pd(OAc)2和n -羟基邻苯二胺（NHPI）为催化剂，亚硝基叔丁基为氮源和氧化剂，研究了将甲基芳烃直接转化为芳香腈的温和氨氧化方法。
From methyl to nitrile: A mild ammoxidation method, which directly converts methyl arenes into aromatic nitriles, has been developed by using Pd(OAc)2 and N-hydroxyphthalimide (NHPI) as the catalysts, and tert-butyl nitrite as the nitrogen source and oxidant.