5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo-niacyclo-tetra-decane bis-(perchlorate) monohydrate.
5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo-niacyclo-tetra-decane bis-(perchlorate) monohydrate.
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DOI：
10.1107/s1600536812012135
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发表时间：
2012-04-01
期刊：
影响因子：
--
通讯作者：
Tiekink ER
中科院分区：
文献类型：
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作者：
Hazari SK;Roy TG;Nath BC;Roy PG;Ng SW;Tiekink ER
In the title hydrated salt, C16H38N4 2+·2ClO4 −·H2O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH3)2– groups. Within the cavity, there are two ammonium–amine N—H⋯N hydrogen bonds. Supramolecular layers are formed in the crystal packing whereby the water molecule links two perchlorate anions, and the resultant aggregates are connected to the dications via N—H⋯O hydrogen bonds. Layers, with an undulating topology, stack along the a axis being connected by C—H⋯O interactions.
