σ-Chelation-directed C-H functionalizations using Pd(II) and Cu(II) catalysts:: regioselectivity, stereoselectivity and catalytic turnover
σ-Chelation-directed C-H functionalizations using Pd(II) and Cu(II) catalysts:: regioselectivity, stereoselectivity and catalytic turnover
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DOI：
10.1039/b611094k
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发表时间：
2006-01-01
影响因子：
3.2
通讯作者：
Chen, Xiao
中科院分区：
文献类型：
--
作者：
Yu, Jin-Quan;Giri, Ramesh;Chen, Xiao
作者小组描述了最近在西格玛螯合引导的C-H功能化方面的进展，以说明在开发以C-H活化为关键步骤的合成有用的催化反应方面的挑战和机遇。重点讨论了在温和条件下发展催化和控制区域选择性和立体选择性的策略。
Recent progress in sigma-chelation directed C-H functionalization from the authors' group is described to illustrate the challenges and opportunities in the development of synthetically-useful catalytic reactions involving C-H activation as the key step. Emphasis is placed on strategies for developing catalysis under mild conditions and controlling regio- and stereoselectivity.