ENTHALPY-ENTROPY COMPENSATION .1. SOME FUNDAMENTAL STATISTICAL PROBLEMS ASSOCIATED WITH ANALYSIS OF VANT HOFF AND ARRHENIUS DATA
ENTHALPY-ENTROPY COMPENSATION .1. SOME FUNDAMENTAL STATISTICAL PROBLEMS ASSOCIATED WITH ANALYSIS OF VANT HOFF AND ARRHENIUS DATA
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DOI：
10.1021/j100562a006
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发表时间：
1976-01-01
影响因子：
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通讯作者：
GRIEGER, RA
中科院分区：
文献类型：
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作者：
KRUG, RR;HUNTER, WG;GRIEGER, RA
对热焓-熵补偿效应进行了统计分析。推导了统计补偿线的相关系数和函数。本文提出了一种假设检验方法，应用于焓-熵数据，以确定是否有任何热力学外因素可从统计补偿效应中区分出来。对文献中报道的补偿的回顾表明，可检测到的热力学外的热焓-熵效应是罕见的。
A statistical analysis of the enthalpy-entropy compensation effect is presented. The correlation coefficient and functionality of the statistical compensation line are derived. A hypothesis test is proposed for applica-tion to enthalpy-entropy data to determine if any extrathermodynamic factors are distinguishable from the statistical compensation effect. A review of reported compensations in the literature reveals that detectable extrathermodynamic enthalpy-entropy effects are rare.