Nanoporous Amino Acid Derived Material Formed via In-Situ Dimerization of Aspartic Acid
Nanoporous Amino Acid Derived Material Formed via In-Situ Dimerization of Aspartic Acid
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DOI：
10.1021/cg100011a
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发表时间：
2010-07-01
影响因子：
3.8
通讯作者：
Rosseinsky, Matthew J.
中科院分区：
文献类型：
--
作者：
Gould, Jamie A.;Bacsa, John;Rosseinsky, Matthew J.
报道了一种新的混合配体三维金属有机骨架，其中一个组分meso-亚氨基二琥珀酸通过天冬氨酸在溶剂热条件下的二聚反应原位形成，刚性柱撑共配体的存在使骨架真正多孔且对客体损失具有鲁棒性。
A new mixed-ligand three-dimensional metal organic framework is reported, where one component, meso-iminodisuccinic acid, is formed in-situ by the dimerization of aspartic acid under solvothermal conditions, The presence of a rigid pillaring co-ligand renders the framework truly porous and robust to guest loss.