Molten salts bearing anion receptor

Molten salts bearing anion receptor
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DOI:
10.1039/b408839e
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发表时间:
2004-01-01
影响因子:
4.9
通讯作者:
Ohno, H
Ohno, H
中科院分区:
化学2区
文献类型:
--
作者:
Matsumi, N;Miyake, M;Ohno, H

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一系列有机硼熔盐是通过烯丙基咪唑鎓型熔盐与各种硼氢化试剂如一溴硼烷二甲硫醚络合物、9-硼双环[3.3.1]壬烷(9-BBN)和均三甲苯硼烷的硼氢化反应制备的,离子电导率为7.79 × 10 ~(-5)~ 6.25 × 10 ~(-6)S cm ~(-1)。323K
A series of organoboron molten salts prepared by hydroboration of allyl imidazolium type molten salts with various hydroborating reagents such as monobromoborane dimethyl sulfide complex, 9-borabicyclo[3.3.1]nonane (9-BBN) and mesitylborane, and subsequent anion exchange reaction exhibited selective cation transporting property with ionic conductivity of 7.79 x 10(-5) - 6.25 x 10(-6) S cm(-1) at 323 K.