A photo-hydrogen-evolving molecular device driving visible-light-induced EDTA-reduction of water into molecular hydrogen
A photo-hydrogen-evolving molecular device driving visible-light-induced EDTA-reduction of water into molecular hydrogen
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DOI：
10.1021/ja058087h
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发表时间：
2006-04-19
影响因子：
15
通讯作者：
Sakai, K
中科院分区：
文献类型：
--
作者：
Ozawa, H;Haga, MA;Sakai, K
由三（2，2 '-联吡啶）钌（II）衍生物和二氯（2，2'-联吡啶）铂（II）衍生物组成的光析氢分子器件已被发现作为“分子器件”的第一个有效模型，该“分子器件”在牺牲电子供体（EDTA）的存在下，在可见光照射下从水中析氢分子。
A photo-hydrogen-evolving molecular device made up of a tris(2,2‘-bipyridine)ruthenium(II) derivative and a dichloro(2,2‘-bipyridine)platinum(II) derivative has been found to serve as the first effective model of a “molecular device” which evolves molecular hydrogen from water in the presence of a sacrificial electron donor (EDTA), under the visible-light illumination.