High-energy ions and atoms sputtered and reflected from a magnetron source for deposition of magnetic thin films

High-energy ions and atoms sputtered and reflected from a magnetron source for deposition of magnetic thin films
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高能离子和原子从磁控管源溅射和反射,用于沉积磁性薄膜

DOI:
10.1116/1.1943452
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发表时间:
2005
期刊:
Journal of Vacuum Science and Technology
影响因子:
--
通讯作者:
H. Sugai
H. Sugai
中科院分区:
--
文献类型:
--
作者:
H. Matsui;H. Toyoda;H. Sugai

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在磁控溅射过程中,粒子对基底的适度轰击会对沉积薄膜产生有利的影响,而过度的高能量轰击可能会导致薄膜损伤和表面粗糙。为了明确这些影响,在磁控溅射 Permalloy™ 靶材 (80%Ni∕20%Fe) 的情况下,通过质谱仪和能量分析仪综合测量高能离子和中性粒子。在低于 4 Pa 的氩气中,通过直流磁控管放电(~600V,<0.2A)从靶材溅射出 Ni 原子,其能量分布函数 (EDF) 扩展至~8eV。对于 Ni+ 离子也观察到类似的 EDF 形状,这些离子可能是由 Ni 原子在气相中的电子轰击电离产生的。 Ar+ 离子的 EDF 具有~150eV 的极高能量尾部。这种高能离子的产生暂时可以用约 600eVAr+ 离子撞击目标表面中和后从目标反射的高能 Ar 原子的共振电荷交换来解释。
In the magnetron sputtering process, moderate bombardment of particles on a substrate gives favorable effects on the deposited films, while excessive bombardment at high energies may cause film damage and surface roughness. To make these influences clear, high-energy ions and neutrals are comprehensively measured by a mass spectrometer with an energy analyzer in the case of magnetron sputtering of a Permalloy™ target (80%Ni∕20%Fe). Ni atoms sputtered from the target by a dc magnetron discharge (∼600V, <0.2A) in argon below 4 Pa have an energy distribution function (EDF) spreading up to ∼8eV. A similar shape of EDF is also observed for Ni+ ions, which are produced possibly by electron-impact ionization of Ni atoms in gas phase. The EDF of Ar+ ions has a tail of extremely high energies of ∼150eV. Production of such energetic ions is tentatively explained in terms of resonant charge exchange of energetic Ar atoms reflected from the target after surface neutralization of ∼600eVAr+ ions impinging on the target...