Asymmetric synthesis of the pyran antibiotic (-)-centrolobine
Asymmetric synthesis of the pyran antibiotic (-)-centrolobine
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DOI：
10.1016/j.tetlet.2005.07.162
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发表时间：
2005-09-26
影响因子：
1.8
通讯作者：
Shyamsunder, T
中科院分区：
文献类型：
--
作者：
Chandrasekhar, S;Prakash, SJ;Shyamsunder, T
以不对称Keck烯丙基化和立体选择性分子内氧迈克尔反应为关键步骤实现了(-)-中心洛宾的全合成，总收率为8%。(C)2005年由爱思唯尔有限公司出版。
An expedient total synthesis of (-)-centrolobine is achieved involving asymmetric Keck allylation and stereoselective intramolecular oxy-Michael reactions as key steps in 8% overall yield. (c) 2005 Published by Elsevier Ltd.