N-confused phlorin: a stable dihydroporphyrin isomer containing a confused pyrrole ring
N-confused phlorin: a stable dihydroporphyrin isomer containing a confused pyrrole ring
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DOI：
10.1142/s1088424614500692
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发表时间：
2014-12
影响因子：
1.5
通讯作者：
Masatoshi Ishida;Kensuke Nakahara;Ryuichi Sakashita;Tomoya Ishizuka;Motonori Watanabe;H. Uno;A. Osuka;H. Furuta
中科院分区：
文献类型：
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作者：
Masatoshi Ishida;Kensuke Nakahara;Ryuichi Sakashita;Tomoya Ishizuka;Motonori Watanabe;H. Uno;A. Osuka;H. Furuta
介绍了以硼氢化钠、对甲苯磺酰肼等为原料，对n -杂卟啉前体进行简单化学还原，合成了n -杂卟啉衍生物。光谱，x射线衍射分析和dft辅助计算支持这些物种的非芳烃的电子结构。
Synthesis of bona fideN-confused phlorin derivatives through simple chemical reduction of N-confused porphyrin precursors using sodium borohydride, p-toluenesulfonyl hydrazide, etc. is described. Spectroscopic, X-ray diffraction analyses and DFT-assisted calculations of these species support the nonaromatic phlorin electronic structure.