Cycfization of the Phosphate Side Chain of Adenosine Triphosphate: Formation of Monoadenosine 5'-Trimetaphosphate
Cycfization of the Phosphate Side Chain of Adenosine Triphosphate: Formation of Monoadenosine 5'-Trimetaphosphate
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三磷酸腺苷的磷酸侧链环化：形成单腺苷 5-三偏磷酸
DOI：
10.1126/science.185.4148.352
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发表时间：
1974
期刊：
影响因子：
56.9
通讯作者：
T. Myers
中科院分区：
文献类型：
--
作者：
T. Glonek;R. Kleps;T. Myers
单腺苷 5'-三偏磷酸是由腺苷 5'-三磷酸通过碳二亚胺介导的缩合制备的。该分子通过3lP核磁共振进行表征，并通过三磷自旋体系的假设模拟其31P谱。该分子具有高反应性，与水接触后迅速转化为三磷酸腺苷。
Monoadenosine 5'-trimetaphosphate has been prepared from adeno-sine 5'-triphosphate by a carbodiimide-mediated condensation. The molecule was characterized by 3lP nuclear magnetic resonance, and its 31P spectrum was simulated through the assumption of a three-phosphorus spin system. The molecule is highly reactive and is rapidly converted to adenosine triphosphate upon contact with water.