Photochemical addition of silirane to endohedral metallofullerene: Electronic properties of carbosilylated Sc3N@Ih-C80
Photochemical addition of silirane to endohedral metallofullerene: Electronic properties of carbosilylated Sc3N@Ih-C80
复制标题
硅烷光化学加成至内嵌金属富勒烯：碳甲硅烷基化 Sc3N@Ih-C80 的电子特性
DOI：
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发表时间：
2016
期刊：
影响因子：
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通讯作者：
T. Akasaka
中科院分区：
文献类型：
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作者：
M. Kako;Takeshi Sugiura;T. Akasaka
Sc 3 N @Ih-C80与硅烷1的光化学反应产生相应的羧甲硅烷基化衍生物。[5，6]-加合物的电化学研究表明，碳硅烷化是适度调节Sc 3 N @Ih-C80电子特性的有效方法。通过密度泛函理论计算，为硅羰基化衍生物的电子性质提供了理论依据。
GRAPHICAL ABSTRACT ABSTRACT The photochemical reaction of Sc3N@Ih-C80 with silirane 1 produced the corresponding carbosilylated derivatives. The electrochemical studies of [5,6]-adducts indicate that carbosilylation is an effective method for tuning moderately the electronic characteristics of Sc3N@Ih-C80. Density functional theory calculations were also conducted to offer a theoretical basis for the electronic properties of carbosilylated derivatives.
影响因子：
15
作者：
Shu, Chunying;Slebodnick, Carla;Gibson, Harry W.
通讯作者：
Gibson, Harry W.