2,4-dichlorophenol oxidation kinetics by Fenton's reagent
2,4-dichlorophenol oxidation kinetics by Fenton's reagent
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DOI：
10.1080/09593331708616506
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发表时间：
1996-12-01
影响因子：
2.8
通讯作者：
Huang, CP
中科院分区：
文献类型：
--
作者：
Tang, WZ;Huang, CP
研究了芬顿试剂氧化2，4-二氯苯酚（2，4-DCP）的动力学和机理。研究了pH值、H_2O_2浓度、Fe ~（2+）浓度和2，4-DCP对氧化脱氯动力学的影响。建立了2，4-DCP在H2 O2和Fe 2+浓度恒定条件下的氧化动力学模型。H2 O2与Fe 2+氧化2，4-DCP的最佳比例被确定为11，这与先前开发的动力学模型预测的相同。
Oxidation kinetics and mechanisms of 2,4-dichlorophenol (2,4-DCP) by Fenton's reagent were studied. The effect of pH, concentration of H2O2, and Fe2+, and 2,4-DCP on both oxidation and dechlorination kinetics was investigated. A mathematical model was developed to describe the kinetics of 2,4-DCP oxidation and chloride ion production at constant concentrations of H2O2, and Fe2+. The optimal ratio of H2O2 to Fe2+ for the oxidation of 2,4-DCP was determined to be 11 which is the same as predicted by the previously developed kinetic model.