Synthesis of two dihydropyrroloindoledione-based copolymers for organic electronics
Synthesis of two dihydropyrroloindoledione-based copolymers for organic electronics
复制标题
DOI：
10.1002/pola.26471
复制
发表时间：
2013-03
期刊：
影响因子：
--
通讯作者：
Joseph W. Rumer;S. Dai;Matthew Levick;Laure Biniek;D. Procter;I. McCulloch
中科院分区：
文献类型：
--
作者：
Joseph W. Rumer;S. Dai;Matthew Levick;Laure Biniek;D. Procter;I. McCulloch
已经以双向方法合成了两种新型的基于二氢吡咯并吲哚二酮（DPID）的共聚物，并对其进行了表征（凝胶渗透色谱法（GPC）、紫外-可见（UV-vis）、循环伏安法和计算模型）。这些平面的，广泛的吸收共聚物显示出用于有机电子学的前景，具有深能级和低带隙。使用的双向Knoevenagel缩合证明了DPID作为有用但未充分开发的共轭单元的多功能性。Wiley Periodicals，Inc. J.波利姆科学，A部分：聚合物2013，51，1285-1291
Two novel dihydropyrroloindoledione (DPID)-based copolymers have been synthesized in a two directional approach and characterized (gel permeation chromatography (GPC), ultra- violet-visible (UV-vis), cyclic voltammetry, and computational models). These planar, broad absorption copolymers show promise for use in organic electronics, with deep energy levels and low bandgaps. The two-directional Knoevenagel condensa- tion used demonstrates the versatility of DPID as a useful yet underexploited conjugated unit. V C 2012 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 1285-1291