Rapid Room Temperature Synthesis of Hexagonal Mesoporous Silica Using Inorganic Silicate Sources and Cationic Surfactants under Highly Acidic Conditions
Rapid Room Temperature Synthesis of Hexagonal Mesoporous Silica Using Inorganic Silicate Sources and Cationic Surfactants under Highly Acidic Conditions
复制标题
高酸性条件下无机硅酸盐源和阳离子表面活性剂室温快速合成六方介孔二氧化硅
DOI：
10.1023/a:1009684801918
复制
发表时间：
1997
影响因子：
2.6
通讯作者：
J. Izumi
中科院分区：
文献类型：
--
作者：
Y. Setoguchi;Y. Teraoka;I. Moriguchi;S. Kagawa;N. Tomonaga;A. Yasutake;J. Izumi
The room-temperature synthesis of mesoporous silica was investigated by using cationic surfactants and inorganic Si sources, like sodium silicate and colloidal silica. Mesoporous silica analogous to the hexagonal MCM-41 could be obtained over a wide range of pH below ca. 11 within short synthesis time (3 h), when the Q4-state Si was absent in the Si source solution prior to mixing with an aqueous solution of cationic surfactants. It was suggested that the strongly acidic conditions (pH < 1) were favorable to give mesoporous silica materials with higher surface area and larger mesopore volume.
