Heterometallic cubane-type clusters [M'Mo3S4] (M' = Au, Ag and Cu): synthesis, structures and electrochemical properties.
Heterometallic cubane-type clusters [M'Mo3S4] (M' = Au, Ag and Cu): synthesis, structures and electrochemical properties.
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DOI：
10.1039/b921176d
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发表时间：
2010-06
影响因子：
4
通讯作者：
Pingping Chen;Yanhui Chen;Yuhan Zhou;Ying Peng;Jingping Qu;M. Hidai
中科院分区：
文献类型：
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作者：
Pingping Chen;Yanhui Chen;Yuhan Zhou;Ying Peng;Jingping Qu;M. Hidai
立方烷型异金属簇合物[（Cp*Mo）（3）（mu（3）-S）（4）Au（PR（3））][PF（6）][X]（Cp* = eta（5）-C（5）Me（5）; 2a：R = Ph，X = BF（4）; 2b：R = Cy，X = PF（6）; 2c：R =（t）Bu，X = PF（6）），[（Cp*Mo）（3）（mu（3）-S）（4）Ag（PPh（3））][PF（6）][OTf]（三、通过[（Cp*Mo）（3）（mu（2）-S）（3）（mu（3）-S）][PF（6）]（1）与配合物[（Cp*Mo）（3）（mu（3）-S）（4）CuI][PF（6）]（4）的反应，R（3）P）Au][X]、[（Ph（3）P）Ag][OTf]和CuI。这些集群已被光谱学和晶体学的特点。此外，还讨论了簇合物2a、2b、2c和4的电化学性质。
The heterometallic cubane-type clusters [(Cp*Mo)(3)(mu(3)-S)(4)Au(PR(3))][PF(6)][X] (Cp* = eta(5)-C(5)Me(5); 2a: R = Ph, X = BF(4); 2b: R = Cy, X = PF(6); 2c: R = (t)Bu, X = PF(6)), [(Cp*Mo)(3)(mu(3)-S)(4)Ag(PPh(3))][PF(6)][OTf] (3, OTf = OSO(2)CF(3)) and [(Cp*Mo)(3)(mu(3)-S)(4)CuI][PF(6)] (4) have been prepared by the reaction of [(Cp*Mo)(3)(mu(2)-S)(3)(mu(3)-S)][PF(6)] (1) with complexes [(R(3)P)Au][X], [(Ph(3)P)Ag][OTf] and CuI, respectively. These clusters have been spectroscopically and crystallographically characterized. In addition, the electrochemical properties of clusters 2a, 2b, 2c and 4 are also discussed.