A single-site hydroxyapatite-bound zinc catalyst for highly efficient chemical fixation of carbon dioxide with epoxides.
A single-site hydroxyapatite-bound zinc catalyst for highly efficient chemical fixation of carbon dioxide with epoxides.
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DOI：
10.1039/b502636a
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发表时间：
2005-06
影响因子：
4.9
通讯作者：
K. Mori;Y. Mitani;Takayoshi Hara;T. Mizugaki;K. Ebitani;K. Kaneda
中科院分区：
文献类型：
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作者：
K. Mori;Y. Mitani;Takayoshi Hara;T. Mizugaki;K. Ebitani;K. Kaneda
一种锌基羟基磷灰石催化剂与刘易斯碱结合被证明是有效的CO2和环氧化物的偶联在大气CO2压力下，在没有额外的有机溶剂的情况下，后处理程序是简单的，催化剂可以重复使用而不损失催化活性和选择性。
A zinc-based hydroxyapatite catalyst in conjunction with a Lewis base proved to be efficient for the coupling of CO2 and epoxide in the absence of additional organic solvents under an atmospheric CO2 pressure; the work-up procedure is straightforward and the catalyst could be reused without loss of catalytic activity and selectivity.