Hydrogenation of a rhodium peroxido complex by formate derivatives: mechanistic studies and the catalytic formation of H2O2 from O2.
Hydrogenation of a rhodium peroxido complex by formate derivatives: mechanistic studies and the catalytic formation of H2O2 from O2.
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DOI：
10.1002/anie.201207073
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发表时间：
2012-12
影响因子：
--
通讯作者：
G. Meier;T. Braun
中科院分区：
文献类型：
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作者：
G. Meier;T. Braun
二氧加氢：由二氧和二氧制备的过氧化铑配合物1，可以用二氢源还原生成过氧化氢。在催化实验中，在1存在的环境条件下，由二氧和甲酸铵生成过氧化氢（见方案）。
Hydrogenation of dioxygen: The rhodium peroxido complex 1, which can be prepared from 2 and dioxygen, can be reduced with dihydrogen sources to yield hydrogen peroxide. In a catalytic experiment, hydrogen peroxide is produced from dioxygen and ammonium formate under ambient conditions in the presence of 1 (see scheme).