High-spin versus spin-crossover versus low-spin: geometry intervention in cooperativity in a 3D polymorphic iron(II)-tetrazole MOFs system.
High-spin versus spin-crossover versus low-spin: geometry intervention in cooperativity in a 3D polymorphic iron(II)-tetrazole MOFs system.
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DOI：
10.1039/c2cc18140a
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发表时间：
2012-03
影响因子：
4.9
通讯作者：
Zheng Yan;Mian Li;Hui-Ling Gao;Xiao-Chun Huang;Dan Li
中科院分区：
文献类型：
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作者：
Zheng Yan;Mian Li;Hui-Ling Gao;Xiao-Chun Huang;Dan Li
本文报道了三种具有化学式[Fe（2）（H（0.67）bdt）（3）]·xH（2）O（H（2）bdt = 5，5 '-（1，4-亚苯基）双（1H-四唑））的3D金属有机骨架（MOF）多晶型物，它们都是由类似的Fe（II）-四唑棒二级结构单元（SBU）通过共价键构建的，但表现出受链间协同性调节的不同自旋状态。
Reported here are three 3D metal-organic framework (MOF) polymorphs with the chemical formula [Fe(2)(H(0.67)bdt)(3)]·xH(2)O (H(2)bdt = 5,5'-(1,4-phenylene)bis(1H-tetrazole)), all of which are constructed from similar Fe(II)-tetrazole rod secondary building units (SBUs) via covalent links, but exhibit diverse spin states regulated by inter-chain cooperativity.