Cyano-Bridged Homochiral Heterometallic Helical Complexes: Synthesis, Structures, Magnetic and Dielectric Properties

Cyano-Bridged Homochiral Heterometallic Helical Complexes: Synthesis, Structures, Magnetic and Dielectric Properties
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氰基桥同手性异金属螺旋配合物:合成、结构、磁性和介电性能

DOI:
10.1021/cg101314j
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发表时间:
2011-01
影响因子:
3.8
通讯作者:
Tong-Bu Lu
Tong-Bu Lu
中科院分区:
化学2区
文献类型:
--
作者:
Xiao-Dan Zheng;Yan-Long Hua;Ren-Gen Xiong;Jia-Zhen Ge;Tong-Bu Lu

文献摘要

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手性大环化合物[Ni(SS-L)](ClO4)2与Na2[Fe(CN)5NO]在乙腈/水中反应得到{[Ni(SS-L)][顺式-Fe(CN)5NO]}n (Δ-2)和{[Ni(SS-L)][反式-Fe(CN)5NO]}n(Λ-3),手性大环化合物[Ni(SS-L)][反式-Fe(CN)5NO]}n(Λ-3)反应生成[Ni(RR-L)](ClO4)2 与 Na2[Fe(CN)5NO]
The reaction of the chiral macrocyclic compound [Ni(SS-L)](ClO4)2 with Na2[Fe(CN)5NO] in acetonitrile/water gave {[Ni(SS-L)][cis-Fe(CN)5NO]}n (Δ-2) and {[Ni(SS-L)][trans-Fe(CN)5NO]}n (Λ-3), and the reaction of chiral [Ni(RR-L)](ClO4)2 with Na2[Fe(CN)5NO]