PREPARATION, PROPERTIES, AND VIBRATIONAL-SPECTRA OF COMPLEXES CONTAINING AUCL2-, AUBR2-, AND AUL2-IONS
PREPARATION, PROPERTIES, AND VIBRATIONAL-SPECTRA OF COMPLEXES CONTAINING AUCL2-, AUBR2-, AND AUL2-IONS
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DOI：
10.1039/dt9730001845
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发表时间：
1973-01-01
期刊：
影响因子：
--
通讯作者：
CLARK, RJH
中科院分区：
文献类型：
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作者：
BRAUNSTE.P;CLARK, RJH
描述了配合物 [Et4N][AuX2] 和 [Bun4N][AuX2]（其中 X = Cl、Br 或 I）的制备和分离。他们的。在每种情况下，盐的拉曼光谱均根据线性阴离子进行解释。将每个阴离子的基频与结构相似的 HgX2 分子的基频进行比较，并给出适当的力常数。
The preparation and isolation of the complexes [Et4N][AuX2] and [Bun4N][AuX2], where X = Cl, Br, or I, are described. The i.r. and Raman spectra of the salts have been interpreted in terms of linear anions in each case. The fundamental frequencies of each anion are compared with those of the structurally similar HgX2 molecules, and appropriate force constants are given.